`); let searchUrl = `/search/`; history.forEach((elem) => { prevsearch.find('#prevsearch-options').append(`
${elem} `); }); } $('#search-pretype-options').empty(); $('#search-pretype-options').append(prevsearch); let prevbooks = $(false); [ {title:"Recently Opened Textbooks", books:previous_books}, {title:"Recommended Textbooks", books:recommended_books} ].forEach((book_segment) => { if (Array.isArray(book_segment.books) && book_segment.books.length>0 && nsegments<2) { nsegments+=1; prevbooks = $(`
${book_segment.title} `); let searchUrl = "/books/xxx/"; book_segment.books.forEach((elem) => { prevbooks.find('#prevbooks-options'+nsegments.toString()).append(`
${elem.title} ${ordinal(elem.edition)} ${elem.author} `); }); } $('#search-pretype-options').append(prevbooks); }); } function anon_pretype() { let prebooks = null; try { prebooks = JSON.parse(localStorage.getItem('PRETYPE_BOOKS_ANON')); }catch(e) {} if ('previous_books' in prebooks && 'recommended_books' in prebooks) { previous_books = prebooks.previous_books; recommended_books = prebooks.recommended_books; if (typeof PREVBOOKS !== 'undefined' && Array.isArray(PREVBOOKS)) { new_prevbooks = PREVBOOKS; previous_books.forEach(elem => { for (let i = 0; i < new_prevbooks.length; i++) { if (elem.id == new_prevbooks[i].id) { return; } } new_prevbooks.push(elem); }); new_prevbooks = new_prevbooks.slice(0,3); previous_books = new_prevbooks; } if (typeof RECBOOKS !== 'undefined' && Array.isArray(RECBOOKS)) { new_recbooks = RECBOOKS; for (let j = 0; j < new_recbooks.length; j++) { new_recbooks[j].viewed_at = new Date(); } let insert = true; for (let i=0; i < recommended_books.length; i++){ for (let j = 0; j < new_recbooks.length; j++) { if (recommended_books[i].id == new_recbooks[j].id) { insert = false; } } if (insert){ new_recbooks.push(recommended_books[i]); } } new_recbooks.sort((a,b)=>{ adate = new Date(2000, 0, 1); bdate = new Date(2000, 0, 1); if ('viewed_at' in a) {adate = new Date(a.viewed_at);} if ('viewed_at' in b) {bdate = new Date(b.viewed_at);} // 100000000: instead of just erasing the suggestions from previous week, // we just move them to the back of the queue acurweek = ((new Date()).getDate()-adate.getDate()>7)?0:100000000; bcurweek = ((new Date()).getDate()-bdate.getDate()>7)?0:100000000; aviews = 0; bviews = 0; if ('views' in a) {aviews = acurweek+a.views;} if ('views' in b) {bviews = bcurweek+b.views;} return bviews - aviews; }); new_recbooks = new_recbooks.slice(0,3); recommended_books = new_recbooks; } localStorage.setItem('PRETYPE_BOOKS_ANON', JSON.stringify({ previous_books: previous_books, recommended_books: recommended_books })); build_popup(); } } var whiletyping_search_object = null; var whiletyping_search = { books: [], curriculum: [], topics: [] } var single_whiletyping_ajax_promise = null; var whiletyping_database_initial_burst = 0; //number of consecutive calls, after 3 we start the 1 per 5 min calls function get_whiletyping_database() { //gets the database from the server. // 1. by validating against a local database value we confirm that the framework is working and // reduce the ammount of continuous calls produced by errors to 1 per 5 minutes. return localforage.getItem('whiletyping_last_attempt').then(function(value) { if ( value==null || (new Date()) - (new Date(value)) > 1000*60*5 || (whiletyping_database_initial_burst < 3) ) { localforage.setItem('whiletyping_last_attempt', (new Date()).getTime()); // 2. Make an ajax call to the server and get the search database. let databaseUrl = `/search/whiletype_database/`; let resp = single_whiletyping_ajax_promise; if (resp === null) { whiletyping_database_initial_burst = whiletyping_database_initial_burst + 1; single_whiletyping_ajax_promise = resp = new Promise((resolve, reject) => { $.ajax({ url: databaseUrl, type: 'POST', data:{csrfmiddlewaretoken: "MDlzHTJxFCUCs4qIw1ay3GVhXtNopV9AR6U73RYTIalJcMVRjG0nwzDEaDMhrQZa"}, success: function (data) { // 3. verify that the elements of the database exist and are arrays if ( ('books' in data) && ('curriculum' in data) && ('topics' in data) && Array.isArray(data.books) && Array.isArray(data.curriculum) && Array.isArray(data.topics)) { localforage.setItem('whiletyping_last_success', (new Date()).getTime()); localforage.setItem('whiletyping_database', data); resolve(data); } }, error: function (error) { console.log(error); resolve(null); }, complete: function (data) { single_whiletyping_ajax_promise = null; } }) }); } return resp; } return Promise.resolve(null); }).catch(function(err) { console.log(err); return Promise.resolve(null); }); } function get_whiletyping_search_object() { // gets the fuse objects that will be in charge of the search if (whiletyping_search_object){ return Promise.resolve(whiletyping_search_object); } database_promise = localforage.getItem('whiletyping_database').then(function(database) { return localforage.getItem('whiletyping_last_success').then(function(last_success) { if (database==null || (new Date()) - (new Date(last_success)) > 1000*60*60*24*30 || (new Date('2023-04-25T00:00:00')) - (new Date(last_success)) > 0) { // New database update return get_whiletyping_database().then(function(new_database) { if (new_database) { database = new_database; } return database; }); } else { return Promise.resolve(database); } }); }); return database_promise.then(function(database) { if (database) { const options = { isCaseSensitive: false, includeScore: true, shouldSort: true, // includeMatches: false, // findAllMatches: false, // minMatchCharLength: 1, // location: 0, threshold: 0.2, // distance: 100, // useExtendedSearch: false, ignoreLocation: true, // ignoreFieldNorm: false, // fieldNormWeight: 1, keys: [ "title" ] }; let curriculum_index={}; let topics_index={}; database.curriculum.forEach(c => curriculum_index[c.id]=c); database.topics.forEach(t => topics_index[t.id]=t); for (j=0; j
Solutions
Textbooks
`); } function build_solutions() { if (Array.isArray(solution_search_result)) { const viewAllHTML = userSubscribed ? `View All` : ''; var solutions_section = $(` Solutions ${viewAllHTML} `); let questionUrl = "/questions/xxx/"; let askUrl = "/ask/question/xxx/"; solution_search_result.forEach((elem) => { let url = ('course' in elem)?askUrl:questionUrl; let solution_type = ('course' in elem)?'ask':'question'; let subtitle = ('course' in elem)?(elem.course??""):(elem.book ?? "")+" "+(elem.chapter?"Chapter "+elem.chapter:""); solutions_section.find('#whiletyping-solutions').append(` ${elem.text} ${subtitle} `); }); $('#search-solution-options').empty(); if (Array.isArray(solution_search_result) && solution_search_result.length>0){ $('#search-solution-options').append(solutions_section); } MathJax.typesetPromise([document.getElementById('search-solution-options')]); } } function build_textbooks() { $('#search-pretype-options').empty(); $('#search-pretype-options').append($('#search-solution-options').html()); if (Array.isArray(textbook_search_result)) { var books_section = $(` Textbooks View All `); let searchUrl = "/books/xxx/"; textbook_search_result.forEach((elem) => { books_section.find('#whiletyping-books').append(` ${elem.title} ${ordinal(elem.edition)} ${elem.author} `); }); } if (Array.isArray(textbook_search_result) && textbook_search_result.length>0){ $('#search-pretype-options').append(books_section); } } function build_popup(first_time = false) { if ($('#search-text').val()=='') { build_pretype(); } else { solution_and_textbook_search(); } } var search_text_out = true; var search_popup_out = true; const is_login = false; function pretype_setup() { $('#search-text').focusin(function() { $('#search-popup').addClass('show'); resize_popup(); search_text_out = false; }); $( window ).resize(function() { resize_popup(); }); $('#search-text').focusout(() => { search_text_out = true; if (search_text_out && search_popup_out) { $('#search-popup').removeClass('show'); } }); $('#search-popup').mouseenter(() => { search_popup_out = false; }); $('#search-popup').mouseleave(() => { search_popup_out = true; if (search_text_out && search_popup_out) { $('#search-popup').removeClass('show'); } }); $('#search-text').on("keyup", delay(() => { build_popup(); }, 200)); build_popup(true); let prevbookUrl = `/search/pretype_books/`; if (is_login) { $.ajax({ url: prevbookUrl, method: 'POST', data:{csrfmiddlewaretoken: "MDlzHTJxFCUCs4qIw1ay3GVhXtNopV9AR6U73RYTIalJcMVRjG0nwzDEaDMhrQZa"}, success: function(response){ previous_books = response.previous_books; recommended_books = response.recommended_books; build_popup(); }, error: function(response){ console.log(response); } }); } else { let prebooks = null; try { prebooks = JSON.parse(localStorage.getItem('PRETYPE_BOOKS_ANON')); }catch(e) {} if (prebooks && 'previous_books' in prebooks && 'recommended_books' in prebooks) { anon_pretype(); } else { $.ajax({ url: prevbookUrl, method: 'POST', data:{csrfmiddlewaretoken: "MDlzHTJxFCUCs4qIw1ay3GVhXtNopV9AR6U73RYTIalJcMVRjG0nwzDEaDMhrQZa"}, success: function(response){ previous_books = response.previous_books; recommended_books = response.recommended_books; build_popup(); }, error: function(response){ console.log(response); } }); } } } $( document ).ready(pretype_setup); $( document ).ready(function(){ $('#search-popup').on('click', '.search-view-item', function(e) { e.preventDefault(); let autoCompleteSearchViewUrl = `/search/autocomplete_search_view/`; let objectUrl = $(this).attr('href'); let selectedId = $(this).data('objid'); let searchResults = []; $("#whiletyping-solutions").find("a").each(function() { let is_selected = selectedId === $(this).data('objid'); searchResults.push({ objectId: $(this).data('objid'), contentType: $(this).data('contenttype'), category: $(this).data('category'), selected: is_selected }); }); $("#whiletyping-books").find("a").each(function() { let is_selected = selectedId === $(this).data('objid'); searchResults.push({ objectId: $(this).data('objid'), contentType: $(this).data('contenttype'), category: $(this).data('category'), selected: is_selected }); }); $.ajax({ url: autoCompleteSearchViewUrl, method: 'POST', data:{ csrfmiddlewaretoken: "MDlzHTJxFCUCs4qIw1ay3GVhXtNopV9AR6U73RYTIalJcMVRjG0nwzDEaDMhrQZa", query: $('#search-text').val(), searchObjects: JSON.stringify(searchResults) }, dataType: 'json', complete: function(data){ window.location.href = objectUrl; } }); }); });
FAQs
Expert-Verified Answer. Answer: The reaction SO₂Cl₂(g)→SO₂(g)+Cl2(g) is a first-order reaction with a half-life of 3.15 ×10⁴s at 320°C. Then 11.2% of SO₂Cl₂ would be decomposed on heating at 320°C for 90 min.
Is the decomposition of SO2Cl2 a first order reaction? ›
SO2Cl2 SO2 + Cl2The rate constant for the reaction is 2.8 x 10-3 min-1 at 600 K.
Is the gas-phase decomposition of SO2Cl2 first order in SO2Cl2? ›
The gas-phase decomposition of SO2Cl2, SO2Cl2(g)→SO2(g)+Cl2(g), is first order in SO2Cl2. At 600 K the half-life for this process is 2.3×105s.
What is the reaction SO2Cl2 gives SO2Cl2? ›
SO2Cl2→SO2+Cl2 is a first order gas reaction with k=2.2×10−5sec−1 at 320oC.
What is the first order rate constant for the decomposition of SO2Cl2? ›
The decomposition of SO2Cl2 is first order in SO2Cl2 and has a rate constant of 1.42×10-4 s^{-1} at a certain temperature.
What is the order of decomposition of SO2Cl2? ›
(a) The gas-phase decomposition of SO2Cl2, SO2Cl21g2 ¡SO21g2 + Cl21g2, is first order in SO2Cl2. At 600 K the half-life for this process is 2.3 * 105 s.
Is decomposition a first order reaction? ›
The decomposition follows two parallel first-order reactions as shown in figure. A substance undergoes first order decomposition. The decomposition follows two parallel first order reactions as K1=1.26×10−4sec−1 and K2=3.8×10−5sec−1.
Is decomposition first or second-order? ›
The decomposition of N2O5 is an example of a first-order reaction, because its rate is proportional to the first power of the concentration (that is, a = 1). The decomposition of NO2 is an example of a second-order reaction, because its rate is proportional to the second power of the concentration (that is, a = 2).
Which reaction is a decomposition reaction? ›
A decomposition reaction occurs when one reactant breaks down into two or more products. This can be represented by the general equation: AB → A + B. Examples of decomposition reactions include the breakdown of hydrogen peroxide to water and oxygen, and the breakdown of water to hydrogen and oxygen.
What is the name of SOCl2 and SO2Cl2? ›
Sulfuryl chloride is commonly confused with thionyl chloride, SOCl2. The properties of these two sulfur oxychlorides are quite different: sulfuryl chloride is a source of chlorine whereas thionyl chloride is a source of chloride ions. An alternative IUPAC name is sulfuroyl dichloride.
There is a subtle difference between reactions of Thionyl Chloride (SOCl2) and Sulfuryl Chloride (SO2Cl2). Basically, thionyl chloride is preferred as a reagent when we need to convert an alcohol to a haloalkane, while sulfuryl chloride is preferred when we need to convert an alkane to a haloalkane.
What are SOCl2 and SO2Cl2 called? ›
Alby Abraham, added an answer, on 27/8/15. Alby Abraham answered this. SOCl2 - Thionyl chloride. SO2Cl2 - sulfuryl Chloride.
Is the reaction SO2Cl2 gives SO2Cl2 exothermic? ›
The reaction, SO2(g)+Cl2(g)⇌SO2Cl2(l) is exothermic and reversible. To the above reaction, at equilibrium, a certain quantity of extra SO2 is introduced keeping the volume constant.
What is formed when sulfuryl chloride SO2Cl2 decomposes at high temperature? ›
Sulfuryl chloride, SO2Cl2(g), decomposes at high temperature to form SO2(g) and Cl2(g). The rate constant at a certain temperature is 4.68x10-5 s-1.
What happens when SO2Cl2 reacts with water? ›
Sulfuryl chloride (SO2Cl2) reacts with water to give a mixture of H2SO4 and HCl.
What is first order reaction with half-life period? ›
The half-life of a reaction is the time required for the reactant concentration to decrease to one-half its initial value. The half-life of a first-order reaction does not depend upon the concentration of the reactant. It is a constant and related to the rate constant for the reaction: t1/2 = 0.693/k.
What is for a first order reaction with half-life? ›
Thus, the half-life of a first-order reaction is given by 0.693/k.
What reaction order is half-life? ›
First-Order Kinetics
In First order reactions, the graph represents the half-life is different from zero order reaction in a way that the slope continually decreases as time progresses until it reaches zero. We can also easily see that the length of half-life will be constant, independent of concentration.
Is half-life a second order reaction? ›
For a zero order reaction (Half life decreases with decreasing concentration.) For a 1st order reaction (Half life is constant.) For a second order reaction (Half life increases with decreasing concentration.)
